Fe3O4 nanopearl decorated carbon nanotubes stemming from carbon onions with self-cleaning and microwave absorption properties

Abstract

Electromagnetic wave absorbing materials with a microwave absorption capacity over a wide frequency range and a superhydrophobic surface are of great importance for their applications in stealth technology, particularly, in high humidity environments. In this paper, Fe₃O₄ nanopearl decorated carbon nanotubes stemming from carbons onions (CNOs/CNTs@Fe₃O₄) have been successfully fabricated using a facile flame strategy, with brass foil as a substrate and catalyst. Fe₃O₄ nanopearls from the thermal decomposition of iron(III) acetylacetonate were in situ decorated on carbon nanotubes stemming from the ripening of the self-assembly of carbon onion aggregates from the incomplete combustion of ethanol. Notably, this nanocomposite film exhibited a good microwave absorption performance with a wide absorption frequency over a range of 6–18 GHz based on the cooperation of the dielectric loss of the carbon nanotubes and the magnetic loss of the Fe₃O₄ nanoparticles. Furthermore, the nanocomposite film displays superhydrophobic properties and a low adhesive force that makes it a good candidate for water shedding stealth materials.