Issue 42, 2015
From the journal:

RSC Advances

Benzyl bromides as aroyl surrogates in substrate directed Pd catalysed o-aroylation†

Ahalya Behera,a   Wajid Ali,a   Srimanta Guin,a   Nilufa Khatun,a   Prakash R. Mohantaa  and  Bhisma K. Patel*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Guwahati, Assam, India
E-mail: patel@iitg.ernet.in
Fax: +91-3612690762

Abstract

An oxidative cross-coupling between directing substrates and benzyl bromides via the combined effect of oxidants TBHP and NMO, catalysed by Pd(II) has been investigated. Benzyl bromides served as efficient aroyl surrogates in this substrate directed C–H functionalisation. The in situ generated benzaldehyde originating from benzyl bromide is the active aroylating source.

Graphical abstract: Benzyl bromides as aroyl surrogates in substrate directed Pd catalysed o-aroylation

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Article information

DOI
https://doi.org/10.1039/C5RA03836G
Article type
Communication
Submitted
04 Mar 2015
Accepted
31 Mar 2015
First published
31 Mar 2015

RSC Adv., 2015,5, 33334-33338

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Benzyl bromides as aroyl surrogates in substrate directed Pd catalysed o-aroylation

A. Behera, W. Ali, S. Guin, N. Khatun, P. R. Mohanta and B. K. Patel, RSC Adv., 2015, 5, 33334 DOI: 10.1039/C5RA03836G

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