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Issue 46, 2015
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Benzylic ethers as arylcarboxy surrogates in substrate directed ortho C–H functionalisation catalysed by copper

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Abstract

A copper catalysed ortho-benzoxylation of 2-arylpyridines has been accomplished using benzylic ethers as the alternative arylcarboxy sources (ArCOO–) via sp2 C–H bond activation. The use of the Pd/TBHP catalytic system is reported to install an o-aroyl (ArCO–) moiety at the 2-arylpyridine while the Cu/TBHP combination fixes a benzoxy (ArCOO–) group at the ortho site.

Graphical abstract: Benzylic ethers as arylcarboxy surrogates in substrate directed ortho C–H functionalisation catalysed by copper

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Supplementary files

Article information


Submitted
25 Feb 2015
Accepted
16 Apr 2015
First published
16 Apr 2015

RSC Adv., 2015,5, 36461-36466
Article type
Communication
Author version available

Benzylic ethers as arylcarboxy surrogates in substrate directed ortho C–H functionalisation catalysed by copper

N. Khatun, A. Banerjee, S. K. Santra, W. Ali and B. K. Patel, RSC Adv., 2015, 5, 36461
DOI: 10.1039/C5RA03462K

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