A ring-opening coupling reaction of D–A cyclopropenes and nitriles is described for the facile synthesis of γ-amino ketones. The co-catalytic system combining copper(I) and boron trifluoride would be inspiring because it disfavors the [3 + 2] cycloaddition to turn the selectivity over the Ritter process.
H. Huang, X. Ji, F. Xiao and G. Deng, RSC Adv., 2015, 5, 26335 DOI: 10.1039/C5RA01541C
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