Mononuclear manganese(iii) complexes of bidentate NO donor Schiff base ligands: synthesis, structural characterization, magnetic and catecholase studies

Abstract

We have synthesized four mononuclear manganese(III) complexes (1–4) of four closely related bidentate NO donor Schiff-base ligands, out of which three (2–4) were structurally characterized. Crystal structure determination reveals that all these complexes are in octahedral geometries. Magnetic studies have been carried out on complexes 2, 3 and 4 in the temperature range 2–300 K under a magnetic field of 0.1 T which yielded negative ZFS parameters of −2.96, –3.51 and −3.72 cm⁻¹ respectively. The catecholase activities of complexes 1–4 have been investigated following the oxidation of 3,5-di-tert-butylcatechol (3,5-DTBC) to 3,5-di-tert-butylbenzoquinone (3,5-DTBQ) with molecular oxygen in DCM at 25 °C, which were found to follow the Michalis–Menton type relation giving the highest TON (K_cat) for the so far reported Mn(III) complexes.