Formation of C(sp2)–S bonds through decarboxylation of α-oxocarboxylic acids with disulfides or thiophenols

Guangwei Rong; Jincheng Mao; Defu Liu; Hong Yan; Yang Zheng; Jie Chen

doi:10.1039/C4RA15751F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Formation of C(sp²)–S bonds through decarboxylation of α-oxocarboxylic acids with disulfides or thiophenols†

Guangwei Rong,^a Jincheng Mao,*^ab Defu Liu,^a Hong Yan,^a Yang Zheng^a and Jie Chen^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China
E-mail: jcmao@suda.edu.cn

^b State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, P. R. China

Abstract

Copper-catalyzed decarboxylative coupling between α-oxocarboxylic acids and diphenyl disulfides or thiophenols is presented, which provided an effective and direct approach for the preparation of useful thioesters through C(sp²)–S bond formation.

Download options Please wait...

Supplementary files

Supplementary information PDF (4525K)

Article information

DOI: https://doi.org/10.1039/C4RA15751F
Article type: Communication
Submitted: 03 Dec 2014
Accepted: 10 Mar 2015
First published: 10 Mar 2015

Download Citation

RSC Adv., 2015,5, 26461-26464

Author version available

Download author version (PDF)

Permissions

Request permissions

Formation of C(sp²)–S bonds through decarboxylation of α-oxocarboxylic acids with disulfides or thiophenols

G. Rong, J. Mao, D. Liu, H. Yan, Y. Zheng and J. Chen, RSC Adv., 2015, 5, 26461 DOI: 10.1039/C4RA15751F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

RSC Advances