Issue 1, 2015
From the journal:

RSC Advances

Brønsted acid-catalyzed hydroarylation of activated olefins†

Ivana Fleischer*ab  and  Jola Pospechb  

* Corresponding authors

a Institut für Organische Chemie, Universität Regensburg, Universitätstrasse 31, 93040 Regensburg, Germany
E-mail: ivana.fleischer@chemie.uni-regensburg.de

b Leibniz Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany

Abstract

A mild, regiospecific Brønsted acid-catalyzed hydroarylation of activated olefins, capable of the formation of quinone methide-like intermediates, has been investigated. Variously substituted 2- and 4-vinylphenols, 4-vinylaniline or 6-vinyl-naphthalen-2-ol were successfully implemented in a sequential protonation and Friedel–Crafts-type alkylation reaction of electron-rich arenes.

Graphical abstract: Brønsted acid-catalyzed hydroarylation of activated olefins

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Article information

DOI
https://doi.org/10.1039/C4RA13647K
Article type
Communication
Submitted
02 Nov 2014
Accepted
17 Nov 2014
First published
19 Nov 2014
This article is Open Access
Creative Commons BY license

RSC Adv., 2015,5, 493-496

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Brønsted acid-catalyzed hydroarylation of activated olefins

I. Fleischer and J. Pospech, RSC Adv., 2015, 5, 493 DOI: 10.1039/C4RA13647K

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