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Issue 8, 2015
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Hydrolytic polycondensation of diethoxydimethylsilane in carbonic acid

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Abstract

A new process for producing silicones based on chlorine-free reagents is suggested. Carbonic acid at elevated pressure and temperature is shown to be an effective reagent for converting alkoxysilane to silicones. The process conditions make it possible to control the ratio between linear and cyclic products.

Graphical abstract: Hydrolytic polycondensation of diethoxydimethylsilane in carbonic acid

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Publication details

The article was received on 01 Nov 2014, accepted on 10 Dec 2014 and first published on 10 Dec 2014


Article type: Communication
DOI: 10.1039/C4RA13619E
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Citation: RSC Adv., 2015,5, 5664-5666

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    Hydrolytic polycondensation of diethoxydimethylsilane in carbonic acid

    A. A. Kalinina, I. V. Elmanovich, M. N. Temnikov, M. A. Pigaleva, A. S. Zhiltsov, M. O. Gallyamov and A. M. Muzafarov, RSC Adv., 2015, 5, 5664
    DOI: 10.1039/C4RA13619E

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