Issue 1, 2015

Poly(benzo[2,1-b:3,4-b′]dithiophene-alt-isoindigo): a low bandgap polymer showing a high open circuit voltage in polymer solar cells

Abstract

A novel optical band gap of 1.57 eV isoindigo (IID)-containing polymer of PBDP-IID was synthesized and the HOMO of the polymer descends to −5.44 eV due to strong electron-deficient isoindigo unit. Bulk heterojunction solar cells made from PBDP-IID exhibited a high Voc of 0.95 V, which shows the highest value among the PSCs based on the narrow bandgap polymer donors with Eg < 1.6 eV.

Graphical abstract: Poly(benzo[2,1-b:3,4-b′]dithiophene-alt-isoindigo): a low bandgap polymer showing a high open circuit voltage in polymer solar cells

Supplementary files

Article information

Article type
Communication
Submitted
11 Oct 2014
Accepted
18 Nov 2014
First published
18 Nov 2014

RSC Adv., 2015,5, 269-273

Author version available

Poly(benzo[2,1-b:3,4-b′]dithiophene-alt-isoindigo): a low bandgap polymer showing a high open circuit voltage in polymer solar cells

M. Wan, H. Zhu, J. Liu and L. Huo, RSC Adv., 2015, 5, 269 DOI: 10.1039/C4RA12171F

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