Issue 1, 2015
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RSC Advances

Circularly polarized luminescence of biaryl atropisomers: subtle but significant structural dependency

Yoko Kitayama,a   Kazuki Nakabayashi,a   Takashi Wakabayashi,a   Nobuo Tajima,b   Michiya Fujiki*c  and  Yoshitane Imai*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan
E-mail: y-imai@apch.kindai.ac.jp

b Computational Materials Science Center, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan

c Graduate School of Materials Science, Nara Institute of Science and Technology, Takayama, Ikoma, Nara 630-0192, Japan
E-mail: fujikim@ms.naist.jp

Abstract

The signs of circularly polarised luminescence and circular dichroism of chiral biaryl fluorophores in the CHCl3-dissolved state (solution state) and the PMMA-film-dispersed state (solid state) were successfully controlled by modifying the internal axial chirality and the axial bonding position of the biaryl units.

Graphical abstract: Circularly polarized luminescence of biaryl atropisomers: subtle but significant structural dependency

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Article information

DOI
https://doi.org/10.1039/C4RA11488D
Article type
Paper
Submitted
30 Sep 2014
Accepted
14 Nov 2014
First published
17 Nov 2014

RSC Adv., 2015,5, 410-415

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Circularly polarized luminescence of biaryl atropisomers: subtle but significant structural dependency

Y. Kitayama, K. Nakabayashi, T. Wakabayashi, N. Tajima, M. Fujiki and Y. Imai, RSC Adv., 2015, 5, 410 DOI: 10.1039/C4RA11488D

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