Issue 9, 2015
From the journal:

RSC Advances

Design of efficient sergeant molecules for chiral induction in nano-porous supramolecular assemblies†

Andrea Minoia,*a   Iris Destoop,b   Elke Ghijsens,b   Steven De Feyter,b   Kazukuni Tahara,c   Yoshito Tobec  and  Roberto Lazzaronia  

* Corresponding authors

a University of Mons – UMONS, Place du Parc 20, 7000 Mons, Belgium
E-mail: andrea.minoia@umons.ac.be
Tel: +32 6537 3859

b Department of Chemistry, Division of Molecular and Nano Materials, KUL, Celestijnenlaan 200F, 3001 Leuven, Belgium

c Division of Frontier Materials Science, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan

Abstract

In this study molecular modeling is used to investigate the transfer of chirality from the molecular level to homochiral, nano-porous 2D networks in self-assembled monolayers at the liquid/graphite interface. This allows proposing design rules for sergeant molecules for inducing chiral supramolecular assembly in nano-porous monolayers.

Graphical abstract: Design of efficient sergeant molecules for chiral induction in nano-porous supramolecular assemblies

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Article information

DOI
https://doi.org/10.1039/C4RA11269E
Article type
Paper
Submitted
26 Sep 2014
Accepted
16 Dec 2014
First published
17 Dec 2014

RSC Adv., 2015,5, 6642-6646

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Design of efficient sergeant molecules for chiral induction in nano-porous supramolecular assemblies

A. Minoia, I. Destoop, E. Ghijsens, S. De Feyter, K. Tahara, Y. Tobe and R. Lazzaroni, RSC Adv., 2015, 5, 6642 DOI: 10.1039/C4RA11269E

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