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Issue 4, 2015
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Au(I) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex, an effective pre-catalyst for Au(I)-catalyzed reactions

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Abstract

A linear η2-alkyne π complex of [Ph3PAu]+, namely Au(I) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex (1), was prepared and characterized. The new complex is found to be shelf-stable and effective for a range of the Au(I)-catalyzed alkyne π activation reactions, including a glycosylation reaction with glycosyl ortho-alkynylbenzoates as donors.

Graphical abstract: Au(i) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex, an effective pre-catalyst for Au(i)-catalyzed reactions

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Publication details

The article was received on 19 Jan 2015, accepted on 08 Feb 2015 and first published on 11 Feb 2015


Article type: Research Article
DOI: 10.1039/C5QO00023H
Citation: Org. Chem. Front., 2015,2, 360-365
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    Au(I) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex, an effective pre-catalyst for Au(I)-catalyzed reactions

    D. Zhu, X. Cao and B. Yu, Org. Chem. Front., 2015, 2, 360
    DOI: 10.1039/C5QO00023H

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