Issue 28, 2015
From the journal:

Polymer Chemistry

Chloride-promoted Pd-catalyzed direct C–H arylation for highly efficient phosphine-free synthesis of π-conjugated polymers†

Shotaro Hayashi*a  and  Toshio Koizumia  

* Corresponding authors

a Department of Applied Chemistry, National Defence Academy, 1-10-20 Hashirimizu, Yokosuka, Japan
E-mail: shayashi@nda.ac.jp

Abstract

We have successfully demonstrated a chloride-promoted Pd-catalyzed phosphine-free direct C–H arylation for highly efficient synthesis of high molecular weight π-conjugated polymers. Among halide ions, chloride ions played a crucial role in highly efficient C–H activation.

Graphical abstract: Chloride-promoted Pd-catalyzed direct C–H arylation for highly efficient phosphine-free synthesis of π-conjugated polymers

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Article information

DOI
https://doi.org/10.1039/C5PY00871A
Article type
Communication
Submitted
08 Jun 2015
Accepted
19 Jun 2015
First published
19 Jun 2015

Polym. Chem., 2015,6, 5036-5039

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Chloride-promoted Pd-catalyzed direct C–H arylation for highly efficient phosphine-free synthesis of π-conjugated polymers

S. Hayashi and T. Koizumi, Polym. Chem., 2015, 6, 5036 DOI: 10.1039/C5PY00871A

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