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Issue 10, 2015
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Polymeric carbon Lewis base–acid adducts: poly(NHC–C60)

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Abstract

Rapid formation of thermally robust polymeric Lewis adducts between the poly(N-heterocyclic carbene) [poly(NHC)] Lewis base and the carbon Lewis acid C60 is utilized to develop a powerful synthetic strategy for the convenient and efficient synthesis of C60-containing polymers with an unprecedented level of C60 incorporation (up to 69.3 wt%). The resulting polymer Lewis adducts, poly(NHC–C60), exhibit several intriguing properties pertaining to their molecular weights, thermal stability, cross-linking, and morphologies of donor(D)/acceptor(A) blends. Most significantly, the morphology of the D/A bulk heterojunction (BHJ) using poly(NHC–C60) appears to be more controlled and the C60 domain size is apparently much smaller and more uniform, as compared to the D/A BHJ directly using C60 with the same D/A ratio.

Graphical abstract: Polymeric carbon Lewis base–acid adducts: poly(NHC–C60)

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Supplementary files

Article information


Submitted
31 Oct 2014
Accepted
11 Dec 2014
First published
02 Jan 2015

Polym. Chem., 2015,6, 1741-1750
Article type
Paper

Polymeric carbon Lewis base–acid adducts: poly(NHC–C60)

M. Hong and E. Y.-X. Chen, Polym. Chem., 2015, 6, 1741
DOI: 10.1039/C4PY01488J

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