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Issue 25, 2015
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meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone

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Abstract

Fusion with a 9,10-anthraquinone moiety was achieved to extend porphyrin's π-system. A bridged dihydroisoindole derivative was used to prepare the corresponding meso-tetraphenyltetraanthraquinonoporphyrin (Ph4TAQP) via a thermal retro-Diels–Alder reaction. The basic optical properties of the prepared new anthraquinonoporphyrin and its complexes with Zn and Pd were studied.

Graphical abstract: meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone

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Supplementary files

Article information


Submitted
01 May 2015
Accepted
14 May 2015
First published
14 May 2015

This article is Open Access

Org. Biomol. Chem., 2015,13, 6977-6983
Article type
Paper
Author version available

meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone

M. A. Filatov, E. Heinrich, K. Landfester and S. Baluschev, Org. Biomol. Chem., 2015, 13, 6977
DOI: 10.1039/C5OB00884K

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