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Issue 19, 2015
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Gold(i)-catalyzed hydroindolylation of allenyl ethers

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Abstract

The gold(I)-catalyzed reaction/rearrangement of allenyl ethers has been investigated in the presence of indoles. Either hydroindolylation or alkylation of an indole with the pendant group of allenyl ether has been observed. The reaction outcome seems to be decided mainly by the nature of the pendant group of the allenyl ether. Control experiments are indicative of an inner sphere mechanism for the hydroindolylation reaction.

Graphical abstract: Gold(i)-catalyzed hydroindolylation of allenyl ethers

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Supplementary files

Article information


Submitted
31 Mar 2015
Accepted
07 Apr 2015
First published
07 Apr 2015

Org. Biomol. Chem., 2015,13, 5358-5362
Article type
Communication
Author version available

Gold(I)-catalyzed hydroindolylation of allenyl ethers

C. N. Kona, M. H. Shinde and C. V. Ramana, Org. Biomol. Chem., 2015, 13, 5358
DOI: 10.1039/C5OB00635J

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