Efficient conversion of ketones into kinetic enol phosphates under mild and accessible conditions has been realised using the developed methods with di-tert-butylmagnesium and bismesitylmagnesium. Optimisation of the quench protocol resulted in high yields of enol phosphates from a range of cyclohexanones and aryl methyl ketones, with tolerance of a range of additional functional units.
W. J. Kerr, D. M. Lindsay, V. K. Patel and M. Rajamanickam, Org. Biomol. Chem., 2015, 13, 10131 DOI: 10.1039/C5OB01849H
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