The potential of TBHP to promote oxidative hydroxylation of α-hydroxy-β-oxophosphonates (HOPs) through C(CO)–C bond cleavage is described. This cleavage, as depicted in the mechanism is expected through an isomer of HOP that reacts with TBHP to generate acids.
S. Battula, A. Kumar and Q. N. Ahmed, Org. Biomol. Chem., 2015, 13, 9953 DOI: 10.1039/C5OB01615K
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