Issue 32, 2015
From the journal:

Organic & Biomolecular Chemistry

Visible light-induced selective hydrobromodifluoromethylation of alkenes with dibromodifluoromethane†

Qing-Yu Lin,a   Xiu-Hua Xua  and  Feng-Ling Qing*ab  

* Corresponding authors

a Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032, China
E-mail: flq@mail.sioc.ac.cn

b College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China

Abstract

A visible light-induced selective hydrobromodifluoromethylation of alkenes using CF2Br2 was developed. This transformation proceeded smoothly in the presence of catalytic eosin Y at room temperature to give various hydrobromodifluoromethylated compounds with broad functional group tolerance.

Graphical abstract: Visible light-induced selective hydrobromodifluoromethylation of alkenes with dibromodifluoromethane

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Article information

DOI
https://doi.org/10.1039/C5OB01302J
Article type
Paper
Submitted
26 Jun 2015
Accepted
13 Jul 2015
First published
13 Jul 2015
This article is Open Access
Creative Commons BY-NC license

Org. Biomol. Chem., 2015,13, 8740-8749

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Visible light-induced selective hydrobromodifluoromethylation of alkenes with dibromodifluoromethane

Q. Lin, X. Xu and F. Qing, Org. Biomol. Chem., 2015, 13, 8740 DOI: 10.1039/C5OB01302J

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