A stereoselective approach to the 8b-azaacenaphthylene ring system is described. This new route features a dichloroketene–enol ether [2 + 2] cycloaddition, a vinylogous Mannich reaction, and an aza-Prins cyclization as key stereoselective transformations.
A. Kamath, C. Fabritius, C. Philouze and P. Delair, Org. Biomol. Chem., 2015, 13, 9834 DOI: 10.1039/C5OB01013F
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