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Issue 31, 2015
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Cascade rearrangement of furylcarbinols with hydroxylamines: practical access to densely functionalized cyclopentane derivatives

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Abstract

This article describes the aza-Piancatelli rearrangement with hydroxylamines to 4-aminocyclopentenones and subsequent transformations that highlight the versatility of the cyclopentene scaffold and the value of the hydroxylamine nucleophile in this transformation.

Graphical abstract: Cascade rearrangement of furylcarbinols with hydroxylamines: practical access to densely functionalized cyclopentane derivatives

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Publication details

The article was received on 09 May 2015, accepted on 02 Jul 2015 and first published on 08 Jul 2015


Article type: Paper
DOI: 10.1039/C5OB00944H
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Citation: Org. Biomol. Chem., 2015,13, 8465-8469

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    Cascade rearrangement of furylcarbinols with hydroxylamines: practical access to densely functionalized cyclopentane derivatives

    G. K. Veits, D. R. Wenz, L. I. Palmer, A. H. St. Amant, J. E. Hein and J. Read de Alaniz, Org. Biomol. Chem., 2015, 13, 8465
    DOI: 10.1039/C5OB00944H

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