SCHEDULED MAINTENANCE
The total synthesis of a number of carbazolo-1,4-quinone natural products using on-water chemistry is described. A recently developed domino ‘in-water, on-water’ process is employed to rapidly and efficiently generate königinequinone A, which subsequently enables access to murrayaquinones B, C, D and E, and pyrayaquinones B and C, via a remarkably facile on-water catalysed Claisen rearrangement.
P. Norcott and C. S. P. McErlean, Org. Biomol. Chem., 2015, 13, 6866 DOI: 10.1039/C5OB00852B
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