Issue 20, 2015
From the journal:

Organic & Biomolecular Chemistry

Direct conversion of allyl arenes to aryl ethylketones via a TBHP-mediated palladium-catalyzed tandem isomerization–Wacker oxidation of terminal alkenes†

JinWu Zhao,a   Li Liu,*b   ShiJian Xiang,b   Qiang Liub  and  HuoJi Chen*b  

* Corresponding authors

a School of Pharmacy, Guangdong Medical College, Songshan Lake Science and Technology Industry Park, Dongguan 523808, P. R. China

b School of Traditional Chinese Medicine, Southern Medical University, Guangzhou, P.R. of China
E-mail: shyshll@sohu.com, chenhuoji2005@126.com
Fax: +86-(020)61648263

Abstract

A TBHP-mediated palladium-catalyzed tandem isomerization–Wacker oxidation of terminal alkenes was developed. This methodology provides a new efficient and simple route for conversion of a range of allyl arenes directly into aryl ethylketones in good yields with high chemoselectivity.

Graphical abstract: Direct conversion of allyl arenes to aryl ethylketones via a TBHP-mediated palladium-catalyzed tandem isomerization–Wacker oxidation of terminal alkenes

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Article information

DOI
https://doi.org/10.1039/C5OB00586H
Article type
Communication
Submitted
24 Mar 2015
Accepted
10 Apr 2015
First published
17 Apr 2015

Org. Biomol. Chem., 2015,13, 5613-5616

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Direct conversion of allyl arenes to aryl ethylketones via a TBHP-mediated palladium-catalyzed tandem isomerization–Wacker oxidation of terminal alkenes

J. Zhao, L. Liu, S. Xiang, Q. Liu and H. Chen, Org. Biomol. Chem., 2015, 13, 5613 DOI: 10.1039/C5OB00586H

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