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Issue 16, 2015
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How to get between the sheets: a review of recent works on the electrochemical exfoliation of graphene materials from bulk graphite

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Abstract

Since the beginning of the ‘graphene era’ post-2004, there has been significant interest in developing a high purity, high yield, and scalable fabrication route toward graphene materials for both primary research purposes and industrial production. One suitable approach to graphene production lies in the realm of electrochemical exfoliation, in which a potential difference is applied between a graphite anode/cathode in the presence of an electrolyte-containing medium. Herein we review various works on the electrochemical fabrication of graphene materials specifically through the use of electrochemical intercalation and exfoliation of a graphite source electrode, focusing on the quality and purity of products formed. We categorise the most significant works in terms of anodic and cathodic control, highlighting the merits of the respective approaches, as well as indicating the challenges associated with both procedures.

Graphical abstract: How to get between the sheets: a review of recent works on the electrochemical exfoliation of graphene materials from bulk graphite

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Publication details

The article was received on 23 Nov 2014, accepted on 28 Jan 2015 and first published on 02 Feb 2015


Article type: Review Article
DOI: 10.1039/C4NR06942K
Citation: Nanoscale, 2015,7, 6944-6956

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    How to get between the sheets: a review of recent works on the electrochemical exfoliation of graphene materials from bulk graphite

    A. M. Abdelkader, A. J. Cooper, R. A. W. Dryfe and I. A. Kinloch, Nanoscale, 2015, 7, 6944
    DOI: 10.1039/C4NR06942K

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