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Issue 6, 2015
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Variation of through-space magnetic response properties upon the formation of cation–π interactions: a survey of [Ag(η-CH2CH2)3]+via DFT calculations

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Abstract

[Ag(η-CH2CH2)3]+ is a prototypical metal–olefin complex displaying cation–π interactions. Herein, we describe the through-space magnetic response to better understand the influence of the metallic center on the organic ligands. The analysis reveals the short- and long-range anisotropic effects produced by Ag+, which influence the C2H4 ligands.

Graphical abstract: Variation of through-space magnetic response properties upon the formation of cation–π interactions: a survey of [Ag(η-CH2CH2)3]+via DFT calculations

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Publication details

The article was received on 25 Feb 2015, accepted on 21 Apr 2015 and first published on 23 Apr 2015


Article type: Letter
DOI: 10.1039/C5NJ00475F
New J. Chem., 2015,39, 4244-4248

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    Variation of through-space magnetic response properties upon the formation of cation–π interactions: a survey of [Ag(η-CH2CH2)3]+via DFT calculations

    J. Camacho Gonzalez, C. Morales-Verdejo and A. Muñoz-Castro, New J. Chem., 2015, 39, 4244
    DOI: 10.1039/C5NJ00475F

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