Issue 9, 2015
From the journal:

New Journal of Chemistry

Asymmetric induction by retgersite, nickel sulfate hexahydrate, in conjunction with asymmetric autocatalysis

Arimasa Matsumoto,a   Hirokazu Ozawa,a   Ayako Inumarua  and  Kenso Soai*a  

* Corresponding authors

a Department of Applied Chemistry, Research Institute for Science and Technology, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan
E-mail: soai@rs.kagu.tus.ac.jp

Abstract

Retgersite, nickel sulfate hexahydrate, forms a chiral crystal with space group P41212 or P43212. A chiral crystal of nickel sulfate hexahydrate was found to act as a chiral initiator of asymmetric autocatalysis, affording highly enantiomerically enriched pyrimidyl alkanols with the corresponding absolute configurations.

Graphical abstract: Asymmetric induction by retgersite, nickel sulfate hexahydrate, in conjunction with asymmetric autocatalysis

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Article information

DOI
https://doi.org/10.1039/C5NJ01459J
Article type
Letter
Submitted
09 Jun 2015
Accepted
15 Jul 2015
First published
16 Jul 2015
This article is Open Access
Creative Commons BY license

New J. Chem., 2015,39, 6742-6745

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Asymmetric induction by retgersite, nickel sulfate hexahydrate, in conjunction with asymmetric autocatalysis

A. Matsumoto, H. Ozawa, A. Inumaru and K. Soai, New J. Chem., 2015, 39, 6742 DOI: 10.1039/C5NJ01459J

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