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Issue 10, 2015
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Reaction of a bulky amine borane with lanthanide trialkyls. Formation of alkyl lanthanide imide complexes

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Abstract

Borane-stabilized lanthanide imides have been synthesized by the reaction of lanthanide trialkyls with a bulky amine borane. X-ray crystal structures indicate the presence of 3-center-2-electron B–H–Ln bonding and Ln–arene interactions in the solid state.

Graphical abstract: Reaction of a bulky amine borane with lanthanide trialkyls. Formation of alkyl lanthanide imide complexes

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Article information


Submitted
29 Apr 2015
Accepted
12 Jun 2015
First published
12 Jun 2015

New J. Chem., 2015,39, 7567-7570
Article type
Letter
Author version available

Reaction of a bulky amine borane with lanthanide trialkyls. Formation of alkyl lanthanide imide complexes

J. Li, D. Gao, H. Hu and C. Cui, New J. Chem., 2015, 39, 7567
DOI: 10.1039/C5NJ01067E

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