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Issue 5, 2015
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Cationic palladium(II) complexes as catalysts for the oxidation of terminal olefins to methyl ketones using hydrogen peroxide

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Abstract

Ligated Pd(II) complexes have been studied for the catalytic oxidation of terminal olefins to their corresponding methyl ketones. The method uses aqueous hydrogen peroxide as the terminal oxidant; a sustainable and readily accessible oxidant. The choice of ligand, counterion and solvent all have a significant effect on catalytic performance and we were able to develop systems which perform well for these challenging oxidations.

Graphical abstract: Cationic palladium(ii) complexes as catalysts for the oxidation of terminal olefins to methyl ketones using hydrogen peroxide

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Publication details

The article was received on 17 Dec 2014, accepted on 05 Mar 2015 and first published on 09 Mar 2015


Article type: Communication
DOI: 10.1039/C4GC02465F
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Citation: Green Chem., 2015,17, 2750-2757
  • Open access: Creative Commons BY license
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    Cationic palladium(II) complexes as catalysts for the oxidation of terminal olefins to methyl ketones using hydrogen peroxide

    Q. Cao, D. S. Bailie, R. Fu and M. J. Muldoon, Green Chem., 2015, 17, 2750
    DOI: 10.1039/C4GC02465F

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