Issue 3, 2015

A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass

Abstract

Current biomass utilization processes do not make use of lignin beyond its heat value. Here we report on a bimetallic Zn/Pd/C catalyst that converts lignin in intact lignocellulosic biomass directly into two methoxyphenol products, leaving behind the carbohydrates as a solid residue. Genetically modified poplar enhanced in syringyl (S) monomer content yields only a single product, dihydroeugenol. Lignin-derived methoxyphenols can be deoxygenated further to propylcyclohexane. The leftover carbohydrate residue is hydrolyzed by cellulases to give glucose in 95% yield, which is comparable to lignin-free cellulose (solka floc). New conversion pathways to useful fuels and chemicals are proposed based on the efficient conversion of lignin into intact hydrocarbons.

Graphical abstract: A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass

Supplementary files

Article information

Article type
Paper
Submitted
01 Oct 2014
Accepted
01 Dec 2014
First published
10 Dec 2014

Green Chem., 2015,17, 1492-1499

Author version available

A synergistic biorefinery based on catalytic conversion of lignin prior to cellulose starting from lignocellulosic biomass

T. Parsell, S. Yohe, J. Degenstein, T. Jarrell, I. Klein, E. Gencer, B. Hewetson, M. Hurt, J. I. Kim, H. Choudhari, B. Saha, R. Meilan, N. Mosier, F. Ribeiro, W. N. Delgass, C. Chapple, H. I. Kenttämaa, R. Agrawal and M. M. Abu-Omar, Green Chem., 2015, 17, 1492 DOI: 10.1039/C4GC01911C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements