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Issue 28, 2015
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First copper(ii) phase M 0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesis

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Abstract

M0.2Mn0.8PS3·0.25H2O materials are obtained by a mild microwave assisted reaction (M′ = CoII, NiII, CuII, ZnII), which permitted us to obtain the first copper(II) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS3.

Graphical abstract: First copper(ii) phase M′0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesis

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Supplementary files

Article information


Submitted
23 Apr 2015
Accepted
04 Jun 2015
First published
04 Jun 2015

Dalton Trans., 2015,44, 12493-12496
Article type
Communication
Author version available

First copper(II) phase M0.2Mn0.8PS3·0.25H2O and analogous M′ = CoII, NiII and ZnII materials obtained by microwave assisted synthesis

P. Fuentealba, C. Cortés, N. Audebrand, E. Le Fur, V. Paredes-García, D. Venegas-Yazigi, J. Manzur and E. Spodine, Dalton Trans., 2015, 44, 12493
DOI: 10.1039/C5DT01540E

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