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Issue 35, 2015
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MeL2Zn2(μ-1,6-Ph2-N6) – a building block for new hexazene complexes

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Abstract

The zinc hexazene complex MeL2Zn2(μ-1,6-Ph2-N6) 1 (MeL = HC[C(Me)N(2,4,6-Me3C6H2)]2) is a suitable hexazene transfer reagent in reactions with main group metal and transition metal complexes containing M–Me units. The reactions proceed with elimination of MeLZnMe and the resulting complexes were characterized by NMR and IR spectroscopy and single crystal X-ray diffraction (5, 8). Quantum chemical calculations were performed to investigate the electronic structure of 5′ and 8′ in more detail and to identify the absorption bands of the hexazene unit.

Graphical abstract: MeL2Zn2(μ-1,6-Ph2-N6) – a building block for new hexazene complexes

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Supplementary files

Article information


Submitted
26 Jun 2015
Accepted
05 Aug 2015
First published
05 Aug 2015

This article is Open Access

Dalton Trans., 2015,44, 15703-15711
Article type
Paper

MeL2Zn2(μ-1,6-Ph2-N6) – a building block for new hexazene complexes

S. Gondzik, C. Wölper, R. Haack, G. Jansen and S. Schulz, Dalton Trans., 2015, 44, 15703
DOI: 10.1039/C5DT02423D

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