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Issue 38, 2015
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Synthesis and post-synthetic modification of amine-, alkyne-, azide- and nitro-functionalized metal–organic frameworks based on DUT-5

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Abstract

Functionalized 4,4′-biphenyldicarboxylic acid molecules with additional amine, alkyne, azide or nitro groups were prepared and applied in the synthesis of novel metal–organic frameworks and mixed-linker metal–organic frameworks isoreticular to DUT-5. The properties of the frameworks could be tuned by varying the number of functional groups in the materials and the amine groups were employed in post-synthetic modification reactions without changing the framework structure or significantly decreasing the porosity of the materials.

Graphical abstract: Synthesis and post-synthetic modification of amine-, alkyne-, azide- and nitro-functionalized metal–organic frameworks based on DUT-5

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Publication details

The article was received on 15 Jun 2015, accepted on 20 Aug 2015 and first published on 24 Aug 2015


Article type: Paper
DOI: 10.1039/C5DT02276B
Citation: Dalton Trans., 2015,44, 16802-16809
  • Open access: Creative Commons BY license
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    Synthesis and post-synthetic modification of amine-, alkyne-, azide- and nitro-functionalized metal–organic frameworks based on DUT-5

    M. A. Gotthardt, S. Grosjean, T. S. Brunner, J. Kotzel, A. M. Gänzler, S. Wolf, S. Bräse and W. Kleist, Dalton Trans., 2015, 44, 16802
    DOI: 10.1039/C5DT02276B

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