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Issue 29, 2015
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Group 1 and 2 cyclic (alkyl)(amino)carbene complexes

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Abstract

The first examples of cyclic (alkyl)(amino)carbene (CAAC) ligands bound to electropositive metal centres (K, Mg, Sr and Ba) have been isolated and characterised. Preliminary studies demonstrate that all complexes are active for polar monomer polymerisation under ambient conditions affording desirable hydroxyl-terminated telechelic polymers.

Graphical abstract: Group 1 and 2 cyclic (alkyl)(amino)carbene complexes

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Publication details

The article was received on 15 Jun 2015, accepted on 24 Jun 2015 and first published on 24 Jun 2015


Article type: Communication
DOI: 10.1039/C5DT02270C
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Citation: Dalton Trans., 2015,44, 12985-12989
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    Group 1 and 2 cyclic (alkyl)(amino)carbene complexes

    Z. R. Turner and J. Buffet, Dalton Trans., 2015, 44, 12985
    DOI: 10.1039/C5DT02270C

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