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Issue 29, 2015
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AEE-active cyclic tetraphenylsilole derivatives with ∼100% solid-state fluorescence quantum efficiency

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Abstract

Two new strongly AEE active (I/I0 ≈ 94) tetraphenylsilole-containing cyclosiloxanes with cyan emissions (λem = 500 nm) and ∼100% solid state fluorescence quantum yields are reported. The intra- and intermolecular C–H⋯π interactions in the crystal play a major role in the observed high solid state fluorescence quantum yields.

Graphical abstract: AEE-active cyclic tetraphenylsilole derivatives with ∼100% solid-state fluorescence quantum efficiency

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Publication details

The article was received on 16 May 2015, accepted on 15 Jun 2015 and first published on 16 Jun 2015


Article type: Communication
DOI: 10.1039/C5DT01846C
Citation: Dalton Trans., 2015,44, 12970-12975

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    AEE-active cyclic tetraphenylsilole derivatives with ∼100% solid-state fluorescence quantum efficiency

    Y. Cai, K. Samedov, B. S. Dolinar, H. Albright, Z. Song, C. Zhang, B. Z. Tang and R. West, Dalton Trans., 2015, 44, 12970
    DOI: 10.1039/C5DT01846C

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