Issue 33, 2015
From the journal:

Dalton Transactions

Synthesis of carboxylate-bridged iron–thiolate clusters from alcohols/aldehydes or carboxylate salts†

Xiaoliang Dong,a   Litao Liu,a   Yuhan Zhou,*a   Jun Liu,a   Yixin Zhang,a   Yanhui Chena  and  Jingping Qu*a  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, School of Pharmaceutical Science and Technology, Dalian University of Technology, Dalian, P.R. China
E-mail: zhouyh@dl.cn, qujp@dlut.edu.cn

Abstract

A series of novel carboxylate-bridged cyclopentadienyl diiron complexes [Cp*Fe(μ-SEt)2(μ-η2-OOCR)FeCp*][PF6] (2, R = H; 3, R = Me; 4, R = Et; 5, R = Pr-n; 6, R = Ph; 7, R = p-Me-C6H4; 8, R = PhCH[double bond, length as m-dash]CH; 9, CH[triple bond, length as m-dash]C) were obtained from alcohols/aldehydes or sodium carboxylates at room temperature. These eight complexes were fully characterized by spectroscopy, and some of them (3, 4, 7 and 8) were further studied by X-ray crystallography. In addition, the electrochemical properties of clusters 2 and 6 are also discussed.

Graphical abstract: Synthesis of carboxylate-bridged iron–thiolate clusters from alcohols/aldehydes or carboxylate salts

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Article information

DOI
https://doi.org/10.1039/C5DT01445J
Article type
Paper
Submitted
16 Apr 2015
Accepted
09 Jul 2015
First published
13 Jul 2015

Dalton Trans., 2015,44, 14952-14958

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Synthesis of carboxylate-bridged iron–thiolate clusters from alcohols/aldehydes or carboxylate salts

X. Dong, L. Liu, Y. Zhou, J. Liu, Y. Zhang, Y. Chen and J. Qu, Dalton Trans., 2015, 44, 14952 DOI: 10.1039/C5DT01445J

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