Issue 20, 2015
From the journal:

Dalton Transactions

Syntheses, structures and theoretical investigations of [Au10S2(PPh2)2(dppma2)4(dppma3)]·[Au6S2(dppma2)2(dppma3)]†‡

Wen Yu,ab   Lukas Guggolz,a   Olaf Fuhr,cd   Dieter Fenske*bcd  and  Stefanie Dehnen*a  

* Corresponding authors

a Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerweinstraße 4, 35043 Marburg, Germany
E-mail: dehnen@chemie.uni-marburg.de
Fax: +4964212825653
Tel: +4964212825751

b Institut für Anorganische Chemie, Karlsruher Institut für Technologie (KIT), Engesserstrasse 15, 76131 Karlsruhe, Germany

c Institut für Nanotechnologie (INT) und Karlsruher Nano-Micro-Facility (KNMF), Karlsruher Institut für Technologie (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

d Lehn Institute of Functional Materials (LIFM), Sun Yat-Sen University, 135 Xingang Road West, Guangzhou 510275, China

Abstract

The synthesis, crystal structure and theoretical studies of a high-nuclear gold(I) complex stabilized by bridging aromatic phosphane ligands are reported. The complex is composed of a neutral Au10 complex unit with a horseshoe-like structure around a neutral Au6 complex unit with a distorted cubane-like structure.

Graphical abstract: Syntheses, structures and theoretical investigations of [Au10S2(PPh2)2(dppma2)4(dppma3)]·[Au6S2(dppma2)2(dppma3)]

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Article information

DOI
https://doi.org/10.1039/C5DT01360G
Article type
Communication
Submitted
13 Mar 2015
Accepted
15 Apr 2015
First published
20 Apr 2015
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2015,44, 9363-9366

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Syntheses, structures and theoretical investigations of [Au10S2(PPh2)2(dppma2)4(dppma3)]·[Au6S2(dppma2)2(dppma3)]

W. Yu, L. Guggolz, O. Fuhr, D. Fenske and S. Dehnen, Dalton Trans., 2015, 44, 9363 DOI: 10.1039/C5DT01360G

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