Issue 31, 2015

Maleimide fused boron–fluorine complexes: synthesis, photophysical and electrochemical properties

Abstract

Novel boron fluorine complex molecules were designed and synthesized using the maleimide core moiety. Significant features such as a large Stoke shift, high quantum yield, and long range absorption and emission wavelengths were observed for these molecules. The lower LUMO level of these molecules indicates their potential application as electron transport materials. The optical band gap was calculated and compared by using UV-absorption edge, density functional theory and electrochemical studies, revealing the charge transfer characteristics.

Graphical abstract: Maleimide fused boron–fluorine complexes: synthesis, photophysical and electrochemical properties

Supplementary files

Article information

Article type
Paper
Submitted
09 Apr 2015
Accepted
25 Jun 2015
First published
25 Jun 2015

Dalton Trans., 2015,44, 13947-13954

Author version available

Maleimide fused boron–fluorine complexes: synthesis, photophysical and electrochemical properties

P. B. Thale, P. N. Borase and G. S. Shankarling, Dalton Trans., 2015, 44, 13947 DOI: 10.1039/C5DT01339A

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