Issue 25, 2015
From the journal:

Dalton Transactions

Extraordinary aluminum coordination in a novel homometallic double complex salt†

Toshihiko Mandai,*a   Hyuma Masub  and  Patrik Johansson ORCID logo ‡a  

* Corresponding authors

a Department of Applied Physics, Chalmers University of Technology, SE-412 96, Göteborg, Sweden
E-mail: mandi@chalmers.se

b Center for Analytical Instrumentation, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba, Japan

Abstract

We have characterized a novel aluminum-based homometallic double complex salt, incorporating discrete octa-coordinated cationic [Al(G3)2]3+ and hexa-coordinated anionic [Al(TfO)4(OH)2]3− complexes (G3 = triglyme, TfO = trifluoromethanesulfonate). X-ray crystallography, Raman spectra, and DFT calculations demonstrate extraordinary weak Al3+ coordination in [Al(G3)2]3+.

Graphical abstract: Extraordinary aluminum coordination in a novel homometallic double complex salt

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Article information

DOI
https://doi.org/10.1039/C5DT01220A
Article type
Communication
Submitted
27 Mar 2015
Accepted
07 May 2015
First published
13 May 2015

Dalton Trans., 2015,44, 11259-11263

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Extraordinary aluminum coordination in a novel homometallic double complex salt

T. Mandai, H. Masu and P. Johansson, Dalton Trans., 2015, 44, 11259 DOI: 10.1039/C5DT01220A

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