Issue 17, 2015
From the journal:

Dalton Transactions

A metal–organic framework constructed using a flexible tripodal ligand and tetranuclear copper cluster for sensing small molecules†

Chaoyi Hou,a   Yue-Ling Bai,*a   XiaoLi Bao,a   Liangzhen Xu,a   Rong-Guang Lin,*b   Shourong Zhu,a   Jianhui Fanga  and  Jiaqiang Xua  

* Corresponding authors

a Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, China
E-mail: yuelingbai@shu.edu.cn

b College of Life Science, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China
E-mail: rglin@fafu.edu.cn

Abstract

A new porous metal–organic framework (MOF) {[Cu4(OH)2(tci)2(bpy)2]·11H2O} (1) based on a tetranuclear copper cluster with intracluster antiferromagnetic interactions was synthesized. Quartz crystal microbalance (QCM) sensor studies reveal sensitive and selective sensing for small molecules.

Graphical abstract: A metal–organic framework constructed using a flexible tripodal ligand and tetranuclear copper cluster for sensing small molecules

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Article information

DOI
https://doi.org/10.1039/C5DT00762C
Article type
Communication
Submitted
21 Feb 2015
Accepted
28 Mar 2015
First published
31 Mar 2015

Dalton Trans., 2015,44, 7770-7773

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A metal–organic framework constructed using a flexible tripodal ligand and tetranuclear copper cluster for sensing small molecules

C. Hou, Y. Bai, X. Bao, L. Xu, R. Lin, S. Zhu, J. Fang and J. Xu, Dalton Trans., 2015, 44, 7770 DOI: 10.1039/C5DT00762C

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