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Issue 24, 2015
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Structure and magnetic properties of an unusual homoleptic iron(III) thiocyanate dimer

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Abstract

We describe the structural and variable temperature magnetic susceptibility properties of an unusual homoleptic bimetallic iron(III) thiocyanate tetraanion. This work represents the first structurally characterized bis(μ-1,3-thiocyanato) dimer of iron(III). A weak antiferromagnetic exchange interaction is observed between the two iron(III) ions, which is supported by broken symmetry density functional theory (DFT) calculations.

Graphical abstract: Structure and magnetic properties of an unusual homoleptic iron(iii) thiocyanate dimer

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Publication details

The article was received on 19 Feb 2015, accepted on 12 May 2015 and first published on 13 May 2015


Article type: Paper
DOI: 10.1039/C5DT00743G
Citation: Dalton Trans., 2015,44, 11077-11082
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    Structure and magnetic properties of an unusual homoleptic iron(III) thiocyanate dimer

    D. R. Dinsdale, A. J. Lough and M. T. Lemaire, Dalton Trans., 2015, 44, 11077
    DOI: 10.1039/C5DT00743G

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