Two-step magnetic switching in a mononuclear iron(II) complex around room temperature

Qian Yang; Xin Cheng; YeXin Wang; BingWu Wang; ZheMing Wang; Song Gao

doi:10.1039/C5DT00585J

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Two-step magnetic switching in a mononuclear iron(ii) complex around room temperature†

Qian Yang,^a Xin Cheng,^a YeXin Wang,^a BingWu Wang,

*^a ZheMing Wang^a and Song Gao*^a

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* Corresponding authors

^a Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
E-mail: wangbw@pku.edu.cn, gaosong@pku.edu.cn

Abstract

A neutral mononuclear Fe(II) complex with spin crossover (SCO) properties, FeL₂(SCN)₂ (1) (L = 2-(2-(trifluoromethyl)phenyl)-1H-imidazo[4,5-f][1,10]phenanthroline), was solvothermally synthesized. It displays a new example of two-step SCO with T_c1↓ = 250 K, T_c1↑ = 260 K and T_c2 = 295 K.

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DOI: https://doi.org/10.1039/C5DT00585J
Article type: Paper
Submitted: 09 Feb 2015
Accepted: 01 Apr 2015
First published: 02 Apr 2015

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Dalton Trans., 2015,44, 8938-8941

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Two-step magnetic switching in a mononuclear iron(II) complex around room temperature

Q. Yang, X. Cheng, Y. Wang, B. Wang, Z. Wang and S. Gao, Dalton Trans., 2015, 44, 8938 DOI: 10.1039/C5DT00585J

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Dalton Transactions

Two-step magnetic switching in a mononuclear iron(ii) complex around room temperature†

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Two-step magnetic switching in a mononuclear iron(II) complex around room temperature

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