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Issue 14, 2015
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A CH2Cl2 complex of a [Rh(pincer)]+ cation

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Abstract

The CH2Cl2 complex [Rh(tBuPONOP)(κ1-ClCH2Cl)][BArF4] is reported, that also acts as a useful synthon for other complexes such as N2, CO and H2 adducts; while the analogous PNP complex undergoes C–Cl activation.

Graphical abstract: A CH2Cl2 complex of a [Rh(pincer)]+ cation

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Article information


Submitted
02 Feb 2015
Accepted
05 Mar 2015
First published
05 Mar 2015

This article is Open Access

Dalton Trans., 2015,44, 6340-6342
Article type
Communication

A CH2Cl2 complex of a [Rh(pincer)]+ cation

G. M. Adams, F. M. Chadwick, S. D. Pike and A. S. Weller, Dalton Trans., 2015, 44, 6340
DOI: 10.1039/C5DT00481K

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