Issue 14, 2015

A CH2Cl2 complex of a [Rh(pincer)]+ cation


The CH2Cl2 complex [Rh(tBuPONOP)(κ1-ClCH2Cl)][BArF4] is reported, that also acts as a useful synthon for other complexes such as N2, CO and H2 adducts; while the analogous PNP complex undergoes C–Cl activation.

Graphical abstract: A CH2Cl2 complex of a [Rh(pincer)]+ cation

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Article information

Article type
02 Feb 2015
05 Mar 2015
First published
05 Mar 2015
This article is Open Access
Creative Commons BY license

Dalton Trans., 2015,44, 6340-6342

A CH2Cl2 complex of a [Rh(pincer)]+ cation

G. M. Adams, F. M. Chadwick, S. D. Pike and A. S. Weller, Dalton Trans., 2015, 44, 6340 DOI: 10.1039/C5DT00481K

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