Issue 9, 2015

The copper(i) metal azolate framework showing unusual coordination mode for the 1,2,4-triazole derivative and photocatalytic activity

Abstract

A unique three-dimensional metal azolate framework containing a tetranuclear copper cluster constructed by six 1,2,4-triazole units was synthesized in which the 1,2,4-triazole units show unusual bridging “crevice” coordination mode with their 1- and 2-positioned sp2 N-atoms as symmetrically bridging centers. The photocatalytic activities of as-prepared compound were tested by degradation of rhodamine-B (RB) under different light irradiation.

Graphical abstract: The copper(i) metal azolate framework showing unusual coordination mode for the 1,2,4-triazole derivative and photocatalytic activity

Supplementary files

Article information

Article type
Communication
Submitted
19 Dec 2014
Accepted
24 Jan 2015
First published
26 Jan 2015

Dalton Trans., 2015,44, 3954-3958

The copper(I) metal azolate framework showing unusual coordination mode for the 1,2,4-triazole derivative and photocatalytic activity

B. Song, C. Qin, Y. Zhang, X. Wu, K. Shao and Z. Su, Dalton Trans., 2015, 44, 3954 DOI: 10.1039/C4DT03933E

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