Issue 4, 2015
From the journal:

Catalysis Science & Technology

Multi-scale promoting effects of lead for palladium catalyzed aerobic oxidative coupling of methylacrolein with methanol†

Junxing Han,a   Suojiang Zhang,*a   Yuchao Liab  and  Ruiyi Yana  

* Corresponding authors

a State Key Lab of Multiphase Complex System, CAS Key Lab of Green Process and Engineering, Beijing Key Lab of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China
E-mail: sjzhang@ipe.ac.cn
Tel: +86 10 82544875

b University of Chinese Academy of Sciences, Beijing, China

Abstract

A highly efficient Pd2Pb8/alumina catalyst was prepared, which provided the highest turnover number (TON) of 302 for aerobic oxidative coupling of methylacrolein with methanol. The enhanced catalytic efficiency could be attributed to the multi-scale (micron, nano and atom scales) promoting effects of the pre-loaded Pb species.

Graphical abstract: Multi-scale promoting effects of lead for palladium catalyzed aerobic oxidative coupling of methylacrolein with methanol

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Article information

DOI
https://doi.org/10.1039/C4CY01729C
Article type
Communication
Submitted
24 Dec 2014
Accepted
27 Feb 2015
First published
02 Mar 2015

Catal. Sci. Technol., 2015,5, 2076-2080

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Multi-scale promoting effects of lead for palladium catalyzed aerobic oxidative coupling of methylacrolein with methanol

J. Han, S. Zhang, Y. Li and R. Yan, Catal. Sci. Technol., 2015, 5, 2076 DOI: 10.1039/C4CY01729C

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