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Issue 35, 2015
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Chirally-modified metal surfaces: energetics of interaction with chiral molecules

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Abstract

Imparting chirality to non-chiral metal surfaces by adsorption of chiral modifiers is a highly promising route to create effective heterogeneously catalyzed processes for the production of enantiopure pharmaceuticals. One of the major current challenges in heterogeneous chiral catalysis is the fundamental-level understanding of how such chirally-modified surfaces interact with chiral and prochiral molecules to induce their enantioselective transformations. Herein we report the first direct calorimetric measurement of the adsorption energy of chiral molecules onto well-defined chirally-modified surfaces. Two model modifiers 1-(1-naphthyl)ethylamine and 2-methylbutanoic acid were used to impart chirality to Pt(111) and their interaction with propylene oxide was investigated by means of single-crystal adsorption calorimetry. Differential adsorption energies and absolute surface uptakes were obtained for the R- and S-enantiomers of propylene oxide under clean ultrahigh vacuum conditions. Two types of adsorption behavior were observed for different chiral modifiers, pointing to different mechanisms of imparting chirality to metal surfaces. The results are analyzed and discussed in view of previously reported stereoselectivity of adsorption processes.

Graphical abstract: Chirally-modified metal surfaces: energetics of interaction with chiral molecules

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Article information


Submitted
22 Jun 2015
Accepted
27 Jul 2015
First published
10 Aug 2015

This article is Open Access

Phys. Chem. Chem. Phys., 2015,17, 22726-22735
Article type
Paper
Author version available

Chirally-modified metal surfaces: energetics of interaction with chiral molecules

P. Dementyev, M. Peter, S. Adamovsky and S. Schauermann, Phys. Chem. Chem. Phys., 2015, 17, 22726
DOI: 10.1039/C5CP03627E

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