Jump to main content
Jump to site search

Issue 12, 2015
Previous Article Next Article

Solvent-tuned dual emission: a structural and electronic interplay highlighting a novel planar ICT (OPICT)

Author affiliations

Abstract

Displaying a dual emission, a Phen-PENMe2 compound can be foreseen as a new model for fundamental studies. It is based on an excited state cumulene-type structure, involving orthogonal π orbital (OPICT). In contrast to the “Twisted Intramolecular Charge Transfer” (TICT) emission, the OPICT emissive state is planar. This new compound is also a potential candidate for local ratiometric probes of medium polarity (mixture of solvents and biological systems) and white emission.

Graphical abstract: Solvent-tuned dual emission: a structural and electronic interplay highlighting a novel planar ICT (OPICT)

Back to tab navigation

Supplementary files

Article information


Submitted
04 Dec 2014
Accepted
16 Feb 2015
First published
17 Feb 2015

Phys. Chem. Chem. Phys., 2015,17, 7639-7642
Article type
Communication
Author version available

Solvent-tuned dual emission: a structural and electronic interplay highlighting a novel planar ICT (OPICT)

S. Chevreux, R. Paulino Neto, C. Allain, K. Nakatani, P. Jacques, I. Ciofini and G. Lemercier, Phys. Chem. Chem. Phys., 2015, 17, 7639
DOI: 10.1039/C4CP05661B

Social activity

Search articles by author

Spotlight

Advertisements