Issue 40, 2015
From the journal:

CrystEngComm

Functionalising metal–organic frameworks with metal complexes: the role of structural dynamics†

Ana E. Platero-Prats,‡abcd   Antonio Bermejo Gómez,§‡ab   Karena W. Chapman,d   Belén Martín-Matute*ab  and  Xiaodong Zou*ac  

* Corresponding authors

a Berzelii Centre EXSELENT on Porous Materials, SE-10691 Stockholm, Sweden
E-mail: xzou@mmk.su.se, belen.martin.matute@su.se

b Department of Organic Chemistry, Stockholm University, SE-10691 Stockholm, Sweden

c Department of Materials and Environmental Chemistry, Stockholm University, SE-10691 Stockholm, Sweden

d X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439, USA

Abstract

A series of iridium-functionalised UiO-67 metal–organic frameworks (MOFs) were synthesised under conditions that simulate kinetically- and thermodynamically-controlled regimes. The degree of functionalisation depends on the reaction time and relative acidity of the native- and metallo-linkers, and can be optimised by controlling the reaction time.

Graphical abstract: Functionalising metal–organic frameworks with metal complexes: the role of structural dynamics

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Article information

DOI
https://doi.org/10.1039/C5CE01732G
Article type
Communication
Submitted
29 Aug 2015
Accepted
11 Sep 2015
First published
14 Sep 2015

CrystEngComm, 2015,17, 7632-7635

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Functionalising metal–organic frameworks with metal complexes: the role of structural dynamics

A. E. Platero-Prats, A. Bermejo Gómez, K. W. Chapman, B. Martín-Matute and X. Zou, CrystEngComm, 2015, 17, 7632 DOI: 10.1039/C5CE01732G

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