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Issue 41, 2015
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Gearing motion in cogwheel pairs of molecular rotors: weak-coupling limit

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Abstract

Variable-temperature (VT) crystal structures, VT 1H spin–lattice relaxation in static crystals, and DFT modelling of the rotational barriers of BCP rotators in crystalline arrays of a rod-like molecule containing two 1,3-bis(ethynyl)bicyclo[1.1.1]pentane (BCP) units demonstrate that a correlated gearing motion occurs in the limit of a weak coupling between two rotors in a pair.

Graphical abstract: Gearing motion in cogwheel pairs of molecular rotors: weak-coupling limit

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Publication details

The article was received on 13 Jul 2015, accepted on 21 Sep 2015 and first published on 22 Sep 2015


Article type: Communication
DOI: 10.1039/C5CE01372K
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Citation: CrystEngComm, 2015,17, 7829-7834
  • Open access: Creative Commons BY-NC license
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    Gearing motion in cogwheel pairs of molecular rotors: weak-coupling limit

    J. Kaleta, J. Michl, C. Mézière, S. Simonov, L. Zorina, P. Wzietek, A. Rodríguez-Fortea, E. Canadell and P. Batail, CrystEngComm, 2015, 17, 7829
    DOI: 10.1039/C5CE01372K

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