Issue 37, 2015
From the journal:

CrystEngComm

[Co(H2O)6]2+ and H3O+ encapsulated in a unique 3D anionic Co(ii) framework with hydrophilic hexagonal and circular channels†

Jun Zhao,a   Bo Liu,b   Ya-Pan Wu,a   Liang Bai,a   Jian Zhanga  and  Dong-Sheng Li*a  

* Corresponding authors

a College of Materials and Chemical Engineering, Hubei Provincial Collaborative Innovation Center for New Energy Microgrid, China Three Gorges University, Yichang 443002, PR China
E-mail: lidongsheng1@126.com

b Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, PR China

Abstract

A new metal–organic framework, [Co(H2O)6·(H3O)]·3[Co2(L)(H2O)2]·0.5H2O (1), has been constructed from Co2 clusters and a biphenyl-pentacarboxylate ligand with open hydrophilic channels. Uniquely, [Co(H2O)6]2+ and H3O+ as guest cations coexist in the channels. The magnetic study indicates that the title compound shows a significantly antiferromagnetic interaction.

Graphical abstract: [Co(H2O)6]2+ and H3O+ encapsulated in a unique 3D anionic Co(ii) framework with hydrophilic hexagonal and circular channels

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Article information

DOI
https://doi.org/10.1039/C5CE01028D
Article type
Communication
Submitted
30 May 2015
Accepted
07 Aug 2015
First published
07 Aug 2015

CrystEngComm, 2015,17, 7034-7037

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[Co(H2O)6]2+ and H3O+ encapsulated in a unique 3D anionic Co(II) framework with hydrophilic hexagonal and circular channels

J. Zhao, B. Liu, Y. Wu, L. Bai, J. Zhang and D. Li, CrystEngComm, 2015, 17, 7034 DOI: 10.1039/C5CE01028D

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